Improving the performance of Ca-alginate films through incorporating zein-caseinate nanoparticles-loaded cinnamaldehyde.

This study aimed to fabricate and characterize the Ca-alginate films functionalized by incorporating zein nanoparticles containing cinnamaldehyde (CA). The zein nanoparticles were coated with Na-caseinate (CN) to inhibit the precipitation of zein in the alginate solution. Afterward, the physical, mechanical, morphological, and barrier properties of the nanocomposite films were evaluated. The particle sizes of different zein nanoparticles (with/without CA and CN) ranged between 43.58 and 251.66 nm. The addition of free CA, zein, and CN nanoparticles significantly increased the thickness, opacity, thermal stability, and water contact angle and improved the mechanical properties of the films. The water vapor permeability was not affected but the antimicrobial activity was improved on fresh-cut apples. The lightness of nanocomposite films decreased and the yellowness and greenness increased. According to SEM and AFM images, a dense and organized interlayer arrangement with a rougher surface was detected in the nanocomposite films. FTIR analysis showed that no new interactions were formed between the Ca-alginate and zein/CN nanoparticles. An excellent sustained CA release into the water was observed for the CA/zein nanoparticles-loaded alginate films. Overall, the results showed that Ca-alginate nanocomposite films of zein nanoparticles have good potential to carry hydrophobic bioactive compounds for specific pharmaceutical and food applications.

Simultaneous Analysis of Mycotoxins, Potentially Toxic Elements, and Pesticides in Rice: A Health Risk Assessment Study.

Rice is a widely consumed food worldwide; however, it can be a source of pollutants, such as potentially toxic elements (PTEs), mycotoxins, and pesticides. Sixty rice samples imported from Pakistan (PAK), India (IND), and Thailand (THAI), as well as domestic Iranian (IRN) rice, were collected from Bushehr, Iran, and investigated for the contamination of PTEs, including arsenic (As), lead (Pb), cadmium (Cd), and nickel (Ni); pesticides, including chlorpyrifos, trichlorfon, diazinon, fenitrothion, and chlorothalonil; mycotoxins, such as aflatoxin B1 (AFB1), zearalenone (ZEN), ochratoxin A (OTA), and deoxynivalenol (DON); and molds. Estimated daily intake (EDI) and hazard quotient (HQ) of pollutants and hazard index (HI) and incremental lifetime cancer risk (ILCR) of rice types for the Iranian adult population were calculated. The content of PTEs in Iranian rice was not higher than Iran's national standard limits. In contrast, other types of rice (imported) had at least one PTE above the permissible level. OTA content was below the detection limit, and all other mycotoxins were within the allowable range in all rice types. Thai rice was the only group without pesticides. The HI order of rice types was as follows: HIPAK = 2.1 > HIIND = 1.86 > HIIRN = 1.01 > HITHAI = 0.98. As was the biggest contributor to the HI of Iranian and Thai rice, and diazinon in the HI of Pakistani and Indian rice. The calculation of ILCR confirmed that the concentrations of Ni and Pb in Pakistani and Ni and As in Indian, Thai, and Iranian rice were not acceptable in terms of lifetime carcinogenic health risks.

Radiation and Internal Loss Engineering of High-Stress Silicon Nitride Nanobeams.

High-stress Si3N4 nanoresonators have become an attractive choice for electro- and optomechanical devices. Membrane resonators can achieve quality factor (Q)-frequency (f) products exceeding 1013 Hz, enabling (in principle) quantum coherent operation at room temperature. String-like beam resonators possess smaller Q × f products; however, on account of their significantly lower mass and mode density, they remain a canonical choice for precision force, mass, and charge sensing, and have recently enabled Heisenberg-limited position measurements at cryogenic temperatures. Here we explore two techniques to enhance the Q of a nanomechanical beam. The techniques relate to two main loss mechanisms: internal loss, which dominates for high aspect ratios and f ≲ 100 MHz, and radiation loss, which dominates for low aspect ratios and f ≳ 100 MHz. First, we show that by embedding a nanobeam in a 1D phononic crystal (PnC), it is possible to localize its flexural motion and shield it against radiation loss. Using this method, we realize f > 100 MHz modes with Q ≈ 104, consistent with internal loss and contrasting sharply with unshielded beams of similar dimensions. We then study the Q × f product of high-order modes of millimeter-long nanobeams. Taking advantage of the mode-shape dependence of stress-induced "loss dilution", we realize a f ≈ 4 MHz mode with Q × f ≈ 9 × 1012 Hz. Our results complement recent work on PnC-based "soft-clamping" of nanomembranes, in which mode localization is used to enhance loss dilution. Combining these strategies should enable ultra-low-mass nanobeam oscillators that operate deep in the quantum coherent regime at room temperature.